INSECTO Mini smoke bomb containing the active ingredient Permethrin. Simply light the non-sparking wick, smoke fumes will work their way into all nooks and crannies killing all flying and crawling insects in treated area. Read the label before use, allow minimum of two hours before ventilating the area well. We recommend using the Insecto mini smoke bomb alongside Perbio Choc for Red Mite control.

PERMETHRIN SMOKE GENERATORS Safety Data Sheet

Page 1 of 12 Safety Data Sheet Revision date: 29-September 2015 replaces all previous editions PERMETHRIN SMOKE GENERATORS SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Trade name PERMETHRIN SMOKE GENERATORS 1.2 Relevant identified uses of the substance or mixture and uses advised against Use Insecticide 1.3 Details of the supplier of the safety data sheet Supplier Lodi UK Ltd Bays 3 & 4, Building 69 Third Avenue Pensnett Trading Estate Kingswinford DY6 7FD United Kingdom Telephone +44 (0) 1384 404242 Telefax +44 (0) 1384 404656 Responsible Department Email: sales@lodi-uk.com 1.4 Emergency telephone no. Emergency telephone no. National Poisons Information Service (NPIS) Phone number : 0344 892 0111 SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Acute toxicity: Category 4 H302 Harmful if swallowed. PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 2 of 12 Skin sensitisation: Category 1 H317 May cause an allergic skin reaction. Eye irritation: Category 2 H319 Causes serious eye irritation. Specific target organ toxicity - single exposure: Category 3 H335 May cause respiratory irritation. Acute aquatic toxicity: Category 1 H400 Very toxic to aquatic life. Chronic aquatic toxicity: Category 1 H410 Very toxic to aquatic life with long lasting effects. Classification according to EU Directives 67/548/EEC or 1999/45/EC Xn Harmful, R22 Xi Irritant, R36/37 Xi Irritant, R43 N Dangerous for the environment, R50/53 2.2 Label elements Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Hazard label for supply/use required. Hazardous components which must be listed on the label: • Permethrin • Potassium chlorate Signal word: Warning Hazard statements H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. EUH401 To avoid risks to human health and the environment, comply with the instructions for use. PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 3 of 12 Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor/ physician. P501 Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as nonhazardous waste. 2.3 Other hazards Cutaneous sensations may occur, such as burning or stinging on the face and mucosae. However, these sensations cause no lesions and are of a transitory nature (max. 24 hours). Ignites readily. Product burns without a flame to give a dense white harmful smoke. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Chemical nature Smoke generator (FU) Permethrin 25/75 13.5% w/w Hazardous components R-phrase(s) according to EC directive 67/548/EEC Hazard statements according to Regulation (EC) No. 1907/2006 Name CASNo. CAS-No. / ECNo. EC Directive 67/548/EEC Regulation (EC) No 1272/2008 Conc. [%] Permethrin 52645-53-1 258-067-9 Xn; R20/22 R43 N; R50/53 Acute Tox. 4, H332 Acute Tox. 4, H302 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 13.50 Potassium chlorate 3811-04-9 223-289-7 O; R 9 Xn; R20/22 N; R51/53 Ox. Sol. 1, H271 Acute Tox. 4, H332 Acute Tox. 4, H302 Aquatic Chronic 2, H411 > 1.00 – < 25.00 Further information Permethrin 52645-53-1 M-Factor: 1,000 (acute) For the full text of the R-phrases/ Hazard statements mentioned in this Section, see Section 16. SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures General advice Remove contaminated clothing immediately and dispose of safely. Inhalation Move the victim to fresh air and keep at rest. Call a physician or poison control center immediately. PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 4 of 12 Skin contact Immediately wash with plenty of soap and water for at least 15 minutes. Warm water may increase the subjective severity of the irritation/paresthesia. This is not a sign of systemic poisoning. In case of skin irritation, application of oils or lotions containing vitamin E may be considered. If symptoms persist, call a physician. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Warm water may increase the subjective severity of the irritation/paresthesia. This is not a sign of systemic poisoning. Apply soothing eye drops, if needed anaesthetic eye drops. Get medical attention if irritation develops and persists. Ingestion Rinse out mouth and give water in small sips to drink. Do NOT induce vomiting. If swallowed, seek medical advice immediately and show this container or label. 4.2 Most important symptoms and effects, both acute and delayed Symptoms Local:, Skin and eye paraesthesia which may be severe, Usually transient with resolution within 24 hours, Skin, eye and mucous membrane irritation, Cough, Sneezing Systemic:, Discomfort in the chest, Tachycardia, Hypotension, Nausea, Abdominal pain, Diarrhoea, Vomiting, Dizziness, Blurred vision, Headache, Anorexia, Somnolence, Coma, Convulsions, Tremors, Prostration, Airway hyperreaction, Pulmonary oedema, Palpitation, Muscular fasciculation, Apathy 4.3 Indication of any immediate medical attention and special treatment needed Risks This product contains a pyrethroid. Pyrethroid poisoning should not be confused with carbamate or organophosphate poisoning. Treatment Local treatment: Initial treatment: symptomatic. Systemic treatment: Initial treatment: symptomatic. Monitor: respiratory and cardiac functions. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. Keep respiratory tract clear. Oxygen or artificial respiration if needed. In case of convulsions, a benzodiazepine (e.g. diazepam) should be given according to standard regimens. If not effective, phenobarbital may be used. Contraindication: atropine. Contraindication: derivatives of adrenaline. There is no specific antidote. Recovery is spontaneous and without sequela PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 5 of 12 SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable High volume water jet 5.2 Special hazards Dangerous gases are evolved in the event of a fire., Contains arising from the potassium chlorate which is classified as an oxidising agent. substance or mixture 5.3 Advice for firefighters Special protective In the event of fire and/or explosion do not breathe fumes. In equipment for fire-fighters the event of fire, wear self-contained breathing apparatus. Further information Remove product from areas of fire, or otherwise cool containers with water in order to avoid pressure being built up due to heat. Whenever possible, contain fire-fighting water by diking area with sand or earth. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Precautions Keep people away from and upwind of spill/leak. Avoid dust formation. Avoid contact with spilled product or contaminated surfaces. When dealing with a spillage do not eat, drink or smoke. 6.2 Environmental Do not allow to get into surface water, drains and ground water. precautions If spillage enters drains leading to sewage works inform local water company immediately. If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone number 0800 807060). 6.3 Methods and materials for containment and cleaning up Methods for cleaning up The nature of this product, when contained in commercial packs, makes spillage unlikely. However, if significant amounts are spilled nevertheless, the following advice is applicable. Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust formation. Clean floors and contaminated objects with plenty of water. Additional advice Check also for any local site procedures. 6.4 Reference to other Information regarding safe handling, see section 7 sections. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13 PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 6 of 12 SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Advice on safe handling No specific precautions required when handling unopened packs/containers; follow relevant manual handling advice. Avoid dust formation. Ensure adequate ventilation. Advice on protection Dust may form explosive mixture in air. against fire and explosion Hygiene measures When using, do not eat, drink or smoke. Remove soiled clothing immediately and clean thoroughly before using again. Contaminated work clothing should not be allowed out of the workplace. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Wash hands immediately after work, if necessary take a shower. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage Store in a place accessible by authorized persons only. areas and containers Keep containers tightly closed in a dry, cool and wellventilated place. Keep away from direct sunlight. Protect from freezing. Advice on common storage Keep away from food, drink and animal feedingstuffs. Suitable materials Polyethylene film within an outer package 7.3 Specific end uses Refer to the label and/or leaflet SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Components CAS-No. Control parameters Update Basis Permethrin 52645-53-1 10 mg/m3 (TWA) OES BCS* *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" 8.2 Exposure controls Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment) Regulations 2004). Engineering controls should be used in preference to personal protective equipment wherever practicable. Refer also to COSHH Essentials. PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 7 of 12 Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection Wear respirator with a particle filter mask (protection factor 4) conforming to European norm EN149FFP1 or equivalent. Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance. Hand protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness of 0,4 mm). Wash when contaminated and dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet. Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent). Skin and body protection Wear standard coveralls and Category 3 Type 4 suit. If there is a risk of significant exposure, consider a higher protective type suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Form powder Colour white to light beige Odour characteristic Ignition temperature > 130 °C Bulk density ca. 940 kg/m3 Water solubility partly soluble Oxidizing properties Contains potassium chlorate which is classified as an oxidising agent. 9.2 Other information Further safety related physical-chemical data are not known. PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 8 of 12 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Thermal decomposition Stable under normal conditions. 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of No hazardous reactions when stored and handled hazardous reactions according to prescribed instructions. 10.4 Conditions to avoid Extremes of temperature and direct sunlight. Heat, flames and sparks. 10.5 Incompatible materials Store only in the original container. 10.6 Hazardous No decomposition products expected under normal decomposition products conditions of use SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute oral toxicity LD50 (rat) ca. 2,000 mg/kg Acute inhalation toxicity LC50 (rat) > 4.2 mg/l Exposure time: 4 h Highest attainable concentration. Irritating to respiratory system. Acute dermal toxicity ATE > 2,000 mg/kg ATE – acute toxicity estimate Skin irritation No skin irritation (rabbit) Eye irritation Irritating to eyes. (rabbit) Sensitisation Sensitising (guinea pig) Information given is based on data on the components and the toxicology of similar products. Assessment repeated dose toxicity Permethrin did not cause specific target organ toxicity in experimental animal studies. Assessment Mutagenicity Permethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Assessment Carcinogenicity Permethrin caused at high dose levels an increased incidence of tumours in mice in the following organ(s): liver, Lungs. The mechanism that triggers tumours in rodents is not relevant for the low exposures encountered under normal use conditions. PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 9 of 12 Assessment toxicity to reproduction Permethrin did not cause reproductive toxicity in a two-generation study in rats. Assessment developmental toxicity Permethrin did not cause developmental toxicity in rats and rabbits. Further information Cutaneous sensations may occur, such as burning or stinging on the face and mucosae. However, these sensations cause no lesions and are of a transitory nature (max. 24 hours). SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to fish LC50 (Poecilia reticulata (guppy)) 0.0076 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient permethrin. Toxicity to aquatic EC50 (Water flea (Daphnia magna)) 0.00017 mg/l invertebrates Exposure time: 48 h The value mentioned relates to the active ingredient permethrin. Toxicity to aquatic plants EC50 (Selenastrum capricornutum) 0.497 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient permethrin. 12.2 Persistence and degradability Biodegradability Permethrin: not rapidly biodegradable Koc Permethrin: Koc: 100000 12.3 Bioaccumulative potential Bioaccumulation Permethrin: Bioconcentration factor (BCF) 300 Does not bioaccumulate. 12.4 Mobility in soil Mobility in soil Permethrin: Immobile in soil 12.5 Results of PBT and vPvB assessment PBT and vPvB assessment Permethrin: This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB). 12.6 Other adverse effects Additional ecological No other effects to be mentioned. information PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 10 of 12 SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant. Advice may be obtained from the local waste regulation authority (part of the Environment Agency in the UK). Contaminated packaging Dispose of empty and cleaned packaging safely. Not completely emptied packagings should be disposed of as hazardous waste. Follow advice on product label and/or leaflet. Waste key for the unused 020108 agrochemical waste containing dangerous product substances SECTION 14: TRANSPORT INFORMATION ADR/RID/ADN 14.1 UN number 14.2 Proper shipping name NOT CLASSIFIED 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environm. Hazardous Mark Hazard no. Tunnel Code IMDG 14.1 UN number 14.2 Proper shipping name NOT CLASSIFIED 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Marine pollutant Segregation group according to IMDG SEGREGATION GROUP IATA 14.1 UN number 14.2 Proper shipping name NOT CLASSIFIED 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environm. Hazardous Mark UK 'Carriage' Regulations 14.1 UN number 14.2 Proper shipping name NOT CLASSIFIED 14.3 Transport hazard class(es) 14.4 Packing group III 14.5 Environm. Hazardous Mark Emergency action code PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 11 of 12 14.6 Special precautions for user See sections 6 to 8 of this Safety Data Sheet. 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No transport in bulk according to the IBC Code. SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture UK and Northern Ireland Regulatory References This material may be subject to some or all of the following regulations (and any subsequent amendments). Users must ensure that any uses and restrictions as indicated on the label and/or leaflet are followed. Transport Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI 2009 No 1348) Merchant Shipping (Dangerous Goods and Marine Pollutants) Regulations 1997 (SI 1997 No 2367) Air Navigation Dangerous Goods Regulations 2002 (SI 2002 No 2786) Supply and Use Chemical (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No 716) Chemical (Hazard Information and Packaging for Supply) (Northern Ireland) Regulations 2009 Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No 2677) EH40 Occupational Exposure Limits - Table 1 List of approved workplace exposure limits Control of Pesticide Regulations 1986 Dangerous Substances and Explosive Atmospheres Regulations 2002 Waste Treatment Environmental Protection Act 1990, Part II Environmental Protection (Duty of Care) Regulations 1991 The Waste Management Licensing Regulations 1994 (as amended) Hazardous Waste Regulations 2005 (Replacing Special Waste Regulations 1996 as amended) Landfill Directive Regulation on Substances That Deplete the Ozone Layer 1994 (EEC/3093/94) Water Resources Act 1991 Anti-Pollution Works Regulations 1999 Further information WHO-classification: III (Slightly hazardous) 15.2 Chemical Safety Assessment A chemical safety assessment is not required. PERMETHRIN SMOKE GENERATORS Safety Data Sheet Page 12 of 12 SECTION 16: OTHER INFORMATION Text of R-phrases mentioned in Section 3 R 9 Explosive when mixed with combustible material. R20/22 Harmful by inhalation and if swallowed. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Text of the hazard statements mentioned in Section 3 H271 May cause fire or explosion; strong oxidiser. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Smoke generators are ready to use products contained in a plastic or aluminium container. The above information is intended to give general health and safety guidance on the storage and transport of the product. It is not intended to apply to the use of the product for which purposes the product label and any appropriate technical usage literature available should be consulted and any relevant licenses, consents or approvals complied with. The requirements or recommendations of any relevant site or working procedure, system or policy in force or arising from any risk assessment involving the substance or product should take precedence over any of the guidance contained in this safety data sheet where there is a difference in the information given. The information provided in this safety data sheet is accurate at the date of publication and will be updated as and when appropriate. No liability will be accepted for any injury, loss or damage resulting from any failure to take account of information or advice contained in this safety data sheet. Reason for Revision: Section 12. Ecological information. Safety Data Sheet according to Regulation (EU) No. 453/2010.